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Beilstein J. Org. Chem. 2011, 7, 151–155, doi:10.3762/bjoc.7.21
Graphical Abstract
Scheme 1: Principle of the photodeconjugation process.
Scheme 2: Enantio- and diastereoselective photodeconjugation reactions.
Figure 1: Natural products prepared by photodeconjugation.
Figure 2: Natural amides possessing the same (6R)-fatty acid side chain.
Scheme 3: Reagents and conditions: (a) NaH, 13a, THF, 25 °C, 83%. (b) KOH, EtOH/H2O (95/5), Δ, 97% (E/Z: 90/1...